Randall D. Kamien, University of Pennsylvania, Philadelphia, PA
We propose a heuristic explanation for the numerous non-close-packed crystal structures observed in various colloidal systems. By developing an analogy between soap froths and the soft coronas of fuzzy colloids, we provide a geometrical interpretation of the free energy of soft spheres. Within this picture, we show that the close-packing rule associated with hard-core interaction and positional entropy of particles is frustrated by a minimum-area principle associated with the soft tail and internal entropy of the soft coronas. We find that the A15 lattice, known to be area minimizing, is favored for a reasonable range of model parameters and so it is among the possible equilibrium states for a variety of colloidal systems. We extend these ideas to diblock copolymers and find new, stable sphere-like phases.
Web Page:
www.physics.upenn.edu/~kamien/kamiengroup/