Tuesday, June 17, 2008 - 4:20 PM
Room 2 (McKimmon Conference Center)
416

The Pair Potential of Colloidal Stars: Microspheres Grafted with Filamentous Bacteriophage

Phil F. Huang1, Karim Addas1, Andy Ward1, Nolan Flynn2, Michael Hagan1, Zvonimir Dogic1, and Seth Fraden1. (1) Brandeis University, Waltham, MA, (2) Wellesley College, Wellesley, MA

We report on the construction of star polymers from polystyrene beads and genetically engineered M13 bacteriophage, a long filamentous particle that forms liquid crystalline phases. The viruses anchored to the spheres undergo a radial-aligned transition at the isotropic-nematic transition of the background solvent. We measure the pair interaction potentials of star polymers using the umbrella sampling method, and investigate the influence of ionic strength and grafting density on the interactions. We found significant discrepancies between the measured interactions and the theoretical predictions based upon the second virial approximation.