Nitrosobenzene (PhNO) undergoes ultraviolet (UV) photodissociation in the gas phase to form a phenyl radical and free NO. Ion imaging and velocity mapping methods determine the vector correlation between the velocity vector and the angular momentum vector in the nascent NO products. There is vector correlation in the free NO. This poster will reveal which of the two limiting vector correlation cases, parallel (or propeller-like) or perpendicular (frisbee-like), is seen in the nascent NO photoproduct from the UV photodissociation of PhNO.