Wednesday, 31 May 2006 - 5:15 PM
Midwest Center 202B (Midwest Airlines Center)
80

Dichromium Bonding in the Ground State

Thomas E. Sorensen and Walter B. England. University of Wisconsin - Milwaukee, Milwaukee, WI

All the important symmetry and chemical effects are described in a consistent fashion. The ground state potential energy curve of Cr2 has a short 3d multiple bond minimum near 3.16 a0 (1.67 Å), a 4s4p metallic feature between 4.8 – 5.2 a0 (2.5 – 2.8 Å), and a possible polarization well beyond 5.7 a0 (3.0 Å). Relativistic effects are thought to be important. These features will be discussed with spectroscopic constants, including a manifold of vibrational levels, and potential energy curves.


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