As part of a continuing study of Pb²⁺ coordination chemistry with TPA, tris-(2-pyridylmethyl) amine, two new compounds have been synthesized. Compound (I), μ-Cl₃[Pb(TPA)]₂Cl_x(OH)_y ∙ zH₂O, is a dimer with three bridging chlorides and exhibits mirror symmetry. It is likely that (I) is a non-stoichiometric salt containing varying amounts of Cl^- and OH^-, as judged by the partial occupancy of the Cl^- not bound to the lead. Compound (II), [Pb(TPA)]₂PbCl₆ ∙, contains a square pyramidal “PbCl₅” structural unit where the Pb²⁺ sits nearly in the basal plane of the square pyramid. This is unexpected on the basis of VSEPR Theory, which predicts that the Pb²⁺ lone pair should manifest itself by a distortion of the structure leading to the Pb²⁺ sitting below the basal plane of the square pyramid.