Ronghua Jin1, Hui Yan1, and Liang T. Chu2. (1) Wadsworth Center, Albany, NY, (2) Wadsworth Center, New York State Department of Health, Albany, NY
Ice and snow are common materials in the environment and reactions over ice surfaces have some significant impact to the atmosphere. Aimed to understand atmospheric S(IV) oxidation processes near ice/snow surfaces and bromine deactivation/activation, we have studied SO2 uptake on HOX-treated ice surfaces and oxalic acid on ice. The study has been carried out in a flow reactor at 190-240 K. Uptake coefficients were determined as a function of surface coverage, temperature, and ice film thickness. Kinetic results are discussed in terms of the Eley-Rideal mechanism. This study suggests that the uptake of SO2 is enhanced by the presence of HOBr or HOCl molecules near the ice surface.
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