Thursday, 5 October 2006
South Ballroom (Binghamton Regency Hotel and Conference Center)
135

Solid state coordination chemistry: Preparation and exercise of 2,2'-bipyrimidine in hydrothermal synthesis

Kristi L. Brown1, N. Gabriel Armatas2, and Jon Zubieta2. (1) St. John Fisher College, Rochester, NY, (2) Syracuse University, Syracuse, NY

The success of procuring a new organometallic structure is vastly dependent on the constituents of the materials. Altering the organonitrogen ligand in a structure has a significant impact on the type of coordination and networking a three dimensional structure will take. The ligand 2,2-bipyrimidine was synthesized using a revised procedure which led to a greater yield than in previous work cited (1). The ligand was then used in several hydrothermal syntheses reactions for which a new and very interesting nickel structure with large pores was obtained. The structure and some information obtained about the structure were reported.

1 Vlad, G., & Horvath, I. T. (2002). Improved syntheis of 2,2'-bipyrimidine. Journal of Organic Chemistry, 67(18), 6550-6552.


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