Thursday, 5 October 2006
South Ballroom (Binghamton Regency Hotel and Conference Center)
176

Preparation of conjugated ruthenium-containing polymers through olefin metathesis for metal incorporation

Danielle E. Schuehler, Joseph E. Williams, and Michael B. Sponsler. Syracuse University, Syracuse, NY

Ruthenium has been incorporated into polyacetylene (PA) by treatment with the olefin metathesis catalyst (H2IMes)RuCl2(=CHPh)(3-bromopyridine)2 (G2B).  Treatment of freshly prepared, porous PA, formed by polymerization of acetylene by G2B, resulted in incorporation of the ruthenium complex into the solid polymer in levels up to 72% by mass, giving metal incorporated polyacetylene (MIPA).  MIPA samples with similar levels (up to 88% by mass) of ruthenium incorporation were obtained by polymerization of acetylene with highly concentrated solutions of G2B, and these materials formed fine suspensions in CH2Cl2.  A variety of experiments confirmed the covalent attachment of ruthenium to the polymer.  Many properties of the MIPAs mimicked those of the untreated polyacetylene, except that the MIPA samples were not conductive even when oxidized or reduced.  MIPA films were obtained by pressing the black powders obtained by either method.

 

                                                                                             


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