Monday, June 30, 2008
Emerald Grand Ballroom (Sheraton Burlington Hotel and Conference Center)
232

Copper Halide Complexes of 2,2'-Dimethyl-4,4'-Bipyridine

David J. Carnevale, Christopher P Landee, and Mark M. Turnbull. Clark University, Worcester, MA

Recent work has shown that reaction of CuX2 (X = Cl, Br) with a variety of pyrazine derivatives (L) leads to formation of the complexes Cu(L)X2 which crystallize as pairs of L-bridged chains linked in pairs by bihalide bridges generating the rails and rungs of a ladder motif, respectively. Preliminary results suggest that the antiferromagnetic exchange through the bihalide bridges does not change significantly from chloride to bromide, which is unexpected given the fact that exchange through bromide is usually significantly stronger, while exchange through the pyrazine-analogue does vary. In an attempt to model these compounds, we are attempting the preparation and analysis of CuX2 complexes of 2,2'-dimethyl-4,4'-bipyridine. Magnetic exchange through the bipyridine should be weak, yielding systems that are effectively equivalent to the isolated rung interactions of the substituted pyrazine compounds. Preliminary results will be presented.