Diana Meza-Figueroa, University of Sonora, Hermosillo Sonora, Mexico
The Hermosillo city in Sonora border state was investigated for its heavy metal (HM) content. Sedimented dust in roofs from 25 elementary schools was analyzed for their contents of Ni, Cr, Zn, Cd, Co, Ba, V, Pb, Fe and Cu. The results of the analysis were used to determine spatial distribution and magnitude of HM pollution. The results of this study reveal that HM distribution is different in two areas of the city. The southern area contains higher concentrations of HM than the northcentral area. The mean level of Cd in exterior dust is 5.65 mg/kg in the southern area whereas the mean level of Cd is 2.83 mg/kg in the northcentral area. Elevated concentrations of Zn (2012 mg/kg), Pb (101.88 mg/kg), Cr (38.13 mg/kg) and Cd (28.38 mg/kg) in roof dust were found in samples located near industrial areas. Principal component analysis (PCA) was applied to the data matrix to evaluate the analytical results and to identify the possible pollution sources of metals. PCA shows two main sources: (1) Pb, Cd, Cr and Zn are mainly derived from industrial sources, combined with traffic sources; (2) Fe, Co and Ba are mainly derived from natural sources. V and Ni are highly correlated and possibly related to fuel combustion processes. Enrichment factors were calculated, which in turn further confirms the source identification. The distribution of the HM in dust does not seem to be controlled only by the topography of the city, but also by the location of the emission sources.
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