Tuesday, 24 May 2005
700

This presentation is part of: Organic Posters

Addition Of Cuprates To Spirodiepoxides Derived From Allenes: A Concise Stereocontrolled Synthesis Of α-Hydroxyketones

Partha Ghosh and Lawrence J. Williams. Rutgers University, Piscataway, NJ

The substituted α-Hydroxyketone containing structural motif is prevalent among natural products like Erythromycins, Amphidinolides etc. We have developed a new methodology for the stereocontrolled synthesis of these classes of motifs by adding cuprates to the spirodiepoxides derived from allenes.


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